The United States Geological Survey said the new quake was relatively shallow and hit near Juchitan, which is a tropical region of Oaxaca state hard hit by another major natural disaster on Sept 7.
Slight quake tremors were felt, and seismic alarms sounded on Saturday in Mexico City, which earlier this week was hit by the country's most deadly natural disaster in decades.
There were no immediate reports of damage or casualties from the new quake, which was smaller and with its epicenter farther to the south than Tuesday's devastating 7.1-magnitude natural disaster that killed almost 300 people.
Alejandra Castellanos was on the second floor of a hotel in a central neighborhood and ran down the stairs and outside with her husband.
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An aftershock rolled through Mexico City Saturday morning, causing residents to flee swaying buildings that were already weakened by an quake that shook the city earlier this week.
However it sparked concern that it could have caused heavy rubble on top of survivors awaiting rescue in Mexico City to shift.
In the stylish Condesa neighborhood, young revelers typically spill out from dimly lit bars and restaurants on a Friday night. Metal gates shuttered others. The Mexico's office of the presidency said the natural disaster has killed 273 people.
"Homes that were still standing just fell down", Ms Cruz said. "They are all moments that you wouldn't wish on anyone".