The victor of 23 Grand Slam singles titles, Williams has been engaged to Ohanian, 34, since December.
The 34-year-old Reddit co-founder proposed to the tennis pro in 2016 at a restaurant in Rome where they first met.
Per People, the pair are getting married this coming weekend in New Orleans, and their guest list is the very definition of lit.
According to Daily Mail, the couple have the Contemporary Arts Center in New Orleans booked for the wedding, set to gulp $1 million.
Guests will not learn the details until Thursday morning.
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Serena has been showing sweet photos of her new baby girl all over social media lately, and in one picture, Alexis and Olympia sat together in the bathtub.
Both parents wouldn't dream of not having her there. Four months later, on April 19, 2017, the couple announced that they were expecting their first child. They are totally and utterly besotted with her'.
Guests will be banned from taking mobile telephones or other electronic devices to the ceremony because Serena has signed an exclusive deal with her British friend Dame Anna Wintour, editor-in-chief of American Vogue, for the glossy magazine to run photographs.
She said: 'I used to think I'd want to retire when I have kids, but no.